99. Solving a chemistry problem
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99. Solving a chemistry problem
3. The catalytic reaction of acetone iodination occurs in a liquid medium. Confirm that between the effective rate constant of this reaction keff and the ionization constant of the acid catalyst K there is a Brønsted correlation relation keff = b(K)n, where b and n are the coefficients of the correlation relationship. Determine graphically the correlation coefficients for these conditions.
Catalyst acid Ionization constant Effective rate constant, dm3(mol*s)
Acetic 1.75*10-5 2.4
Chropropionic 1.01*10-4 5.9
Monochloroacetic 1.38*10-3 29
Trichloroacetic 2.2*10-2 120
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