27. Solving a chemistry problem

27. Solving a chemistry problem

1. In standard solutions of potassium salt with SA concentration, the electrode potentials of the potassium-selective electrode relative to the silver-silver chloride electrode were measured and the following data were obtained:
Sk, mol/l 1.0*10-1 1.0*10-2 1.0*10-3 1.0*10-4
E, mV 100 46.0 -7.00 -60.0
Based on these data, a calibration graph was constructed in E - pCK coordinates. A sample weighing 0.2000 g containing potassium was dissolved in water and the volume was brought to V (ml). Then we measured the electrode potential of the potassium selective electrode (EX) in the resulting solution:
Task
V, ml 100
EX,mV 60
Calculate the mass fraction (%) of potassium in the sample.

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