2. Solving a chemistry problem

2. Solving a chemistry problem

5. To construct a calibration graph for the determination of cadmium, a standard solution of cadmium salt C(1/2Cd2+)=1*10-4 mol*l-1 was used. Aliquots of this solution Vst (1.0; 2.0; 3.0; 4.0; 5.0; 6.0 ml) were diluted with the background in the cell to 25.0 ml and polarographed. In doing so, the following data was obtained:
Vst, ml 1.0 2.0 3.0 4.0 5.0 6.0
h, mm 9.0 16.0 26.5 35.0 41.0 54.0
A portion m (g) of an alloy containing cadmium was dissolved in nitric acid, the acid was removed by evaporation, the residue was diluted to volume V (ml). A 5.0 ml aliquot was introduced into the well and the volume was adjusted to 25.0 ml with background. During polarography under the same conditions as standard solutions, the following data were obtained:
option m, g V, ml h, mm
4 1,000 250 24.7
Calculate the mass fraction w (%) of cadmium in the sample of the alloy.

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