87. Solving a chemistry problem

87. Solving a chemistry problem

35th century To construct a calibration curve for the nephelometric determination of the sulfate ion, 25.0 ml of an H2SO4 solution containing 0.215 mg/ml SO3 was placed in a 100 ml volumetric flask. Then in 100 ml volumetric flasks containing 20.0; 15.0; 10.0; 6.00 and 2.00 ml of this solution, prepared suspensions of BaSO4 and measured their apparent absorbances:

, ml
20.00 15.00 10.00 6.00 2.00
Dx, ap 0.51 0.62 0.80 0.98 1.22

Based on these data, a calibration graph was constructed. The analyzed solution (50.0 ml) was diluted in a 100 ml volumetric flask. Then 20.0 ml of this solution was transferred into a 100 ml volumetric flask. a suspension of BaSO4 was prepared in it and brought to the mark with water. The apparent optical density of this solution turned out to be:
Options a b c d
Dx,app 0.72 0.54 1.08 0.90
Determine the content of SO3 in the solution (mg/l).

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